Effects of in Vitro Glycation on Fe3+ Binding and Fe3+ Isoforms of Transferrin

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Effects of in vitro glycation on Fe3+ binding and Fe3+ isoforms of transferrin.

BACKGROUND In diabetes, protein function is altered by glycation, but the impact on the Fe3+ binding and antioxidant functions of transferrin (Tf) is largely unknown. The aim of the present study was to investigate the effects of glycation on the distribution of Fe3+ on the two Fe3+ -binding sites of Tf. METHODS In vitro glycation of Tf was accomplished by preincubation with glucose for 14 da...

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The Fe(3+) binding site of recombinant nFbp, a ferric-binding protein found in the periplasmic space of pathogenic Neisseria, has been characterized by physicochemical techniques. An effective Fe(3+) binding constant in the presence of 350 microm phosphate at pH 6.5 and 25 degrees C was determined as 2.4 x 10(18) m(-1). EPR spectra for the recombinant Fe(3+)nFbp gave g' = 4.3 and 9 signals char...

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Study of Nonenzymatic Glycation of Transferrin and its Effect on Iron -Binding Antioxidant Capacity

Objective(s) Nonenzymatic glycosylation (glycation) occurs in many macromolecules in aging and diabetes due to exposure of biomolecules to high level of glucose. Glycation can changes function, activities and structure of many biomolecules. Considering this important role of transferrin (Trf) in iron transport and antioxidant activity in plasma this study was carried out to investigate the eff...

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ژورنال

عنوان ژورنال: Clinical Chemistry

سال: 2004

ISSN: 0009-9147,1530-8561

DOI: 10.1373/clinchem.2004.033811